کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5148114 | 1497376 | 2017 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A new study on improving the physicochemical and electrochemical properties of SPEEK nanocomposite membranes for medium temperature proton exchange membrane fuel cells using different loading of zirconium oxide nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The present research focused on investigation of physicochemical and electrochemical properties of proton exchange membranes based on sulfonated poly (ether ether ketone) (SPEEK) by using zirconia nanoparticles. Plain and nanocomposite SPEEK membranes with different loadings of microwave-induced gel combustion synthesized ZrO2 were fabricated. Sulfonation of polymer and nanoparticle production was confirmed by H NMR and XRD, respectively. Physical, chemical, and electrochemical properties of membranes were investigated by SEM, IEC, WU, EIS, tensile stress-strain, TGA, Fenton, and hydrolytic stability tests. H NMR spectra represented a DS of 65% for the sulfonated polymer. The prepared nanocomposite membranes possess improved thermal and mechanical stability with higher hydrolytic stability and enhanced oxidative stability. In addition, nanocomposite membranes exhibited higher water uptake with lower IEC. The hygroscopic zirconia nanoparticles resulted higher proton conductivity of nanocomposite membranes at temperatures upper than 80 °C in comparison with pristine SPEEK membrane. All results showed the fabricated nanocomposite membranes have good physicochemical properties and promising future of the introduced approach for PEMFC applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 1, 5 January 2017, Pages 590-602
Journal: International Journal of Hydrogen Energy - Volume 42, Issue 1, 5 January 2017, Pages 590-602
نویسندگان
Fatemeh Gashoul, Mohammad Javad Parnian, Soosan Rowshanzamir,