کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5207482 | 1382353 | 2009 | 4 صفحه PDF | دانلود رایگان |
The synchronous scan spectra (SSS) technique was successfully applied to monitor the macromolecular chain motions near the glass transition temperature in polystyrene (PS) and poly (vinyl methyl ether) (PVME) films on a copper substrate. In SSS of PS and PVME films, two peaks at 467Â nm and 473Â nm, which correlated to the light source spectrum of the spectrofluorimeter, were used to characterize the glass transition of polymers. By monitoring the intensity of peaks at 467 and 473Â nm in the spectra, the intensity-temperature curves exhibited kinks near the glass transition. The kinks have also been shown in plots of IR473/IR467vs. temperature, which implies the distinct fluctuation of SSS intensity distribution at the glass transition temperature of the polymer. As a spectroscopy measurement method with simplicity, rapidity and sensitivity, the SSS method was proved to be able to monitor the glass transition in polymers, which has been commonly measured by differential scanning calorimetry (DSC).
Journal: Polymer Testing - Volume 28, Issue 2, April 2009, Pages 165-168