کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5391232 | 1505173 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Near infrared photodissociation spectra of the aniline+-argon ionic complexes
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The near infrared spectra of the ionic complexes aniline(NH2)+-argon and aniline(ND2)+-argon have been measured by laser photodissociation spectroscopy. The bands observed from 10Â 500 to 13Â 500Â cmâ1 have been assigned to the D1(Aâ¼2A2)âD0(Xâ¼2B1) electronic transition within the solvated chromophore. They are characterized by a long vibrational progression involving the 6a mode. On the basis of CASSCF calculations, a large change of geometry along this coordinate is found while the amino group remains in the ring plane. Therefore, a change of the conjugation of the ring rather than a charge transfer is inferred. This is thought to be the origin of the extent of the progression.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics Letters - Volume 419, Issues 4â6, 26 February 2006, Pages 356-361
Journal: Chemical Physics Letters - Volume 419, Issues 4â6, 26 February 2006, Pages 356-361
نویسندگان
T. Pino, S. Douin, N. Boudin, Ph. Bréchignac,