کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5421886 | 1507893 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Growth of Fe3O4(001) thin films on Pt(100): Tuning surface termination with an Fe buffer layer
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We studied the preparation of well-ordered thin Fe3O4(001) films on a metallic substrate, Pt(100), using LEED and STM. The results show that film growth either by Fe reactive deposition in oxygen or by deposition-oxidation cycles onto pure Pt(100) results primarily in (111)-oriented surfaces. To grow Fe3O4(001) films, the preparation must include deposition of an Fe buffer layer as previously suggested for the growth of Fe3O4(001) on MgO(001) (Spiridis et al. Phys. Rev. B 74 (2006) 155423). Two stable (so called “dimer”- and B-layer) surface terminations were observed, both exhibiting a (â2Â ÃÂ â2)R450 reconstruction. Several intermediate, Fe-rich terminations were observed during the annealing process of an initially dimer-like structure. The process critically depends on the thickness of the buffer layer, which can be used as a tuning parameter for surface structures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 636, June 2015, Pages 42-46
Journal: Surface Science - Volume 636, June 2015, Pages 42-46
نویسندگان
Earl M. Davis, Ke Zhang, Yi Cui, Helmut Kuhlenbeck, Shamil Shaikhutdinov, Hans-Joachim Freund,