کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5425396 | 1395855 | 2007 | 10 صفحه PDF | دانلود رایگان |
The charge transfer between Hâ and a free-electron vicinal metallic surface is studied using a wave-packet propagation method. We apply a statistical Thomas-Fermi-von Weizsäcker model with a local density approximation for the exchange-correlation energy to compute the ground-state electronic structure of the substrate. The long-range image charge effects in the electron transfer are included on a phenomenological level. We obtain the ion-survival probability from a rate equation for a set of realistic scattering trajectories of projectiles that are incident with a kinetic energy of 50Â eV. Our calculations reveal a pronounced substrate orientation dependence of the charge transfer dynamics expressed in a “left-right” (or “step-up-step-down”) scattering asymmetry in the final ion-survival probability, which is caused by an enhancement of electron loss on the outgoing part of those ion trajectories which approach steps from below.
Journal: Surface Science - Volume 601, Issue 3, 1 February 2007, Pages 622-631