کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
5435702 1398119 2018 9 صفحه PDF ندارد دانلود رایگان
عنوان انگلیسی مقاله
Metastable solidification of hypereutectic Co2Si-CoSi composition: Microstructural studies and in-situ observations
کلمات کلیدی
Co-Si system; Undercooling; Metastable phase; X-ray diffraction; Microstructure formation;
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Metastable solidification of hypereutectic Co2Si-CoSi composition: Microstructural studies and in-situ observations
چکیده انگلیسی

Metastable solidification of undercooled Co60Si40 melts was investigated by microstructural studies and in-situ high-energy X-ray diffraction. Five solidification paths were identified. Three of them were observed at low undercoolings, which show uncoupled and coupled growth of stable β-Co2Si and CoSi compounds. The other paths were observed at high undercoolings, which show peritectic and primary crystallization of a metastable Co5Si3 compound. The β-Co2Si and Co5Si3 compounds crystallize into a hexagonal crystal structure and experience solid-state decomposition. Microstructure formation depends on solidification path. The coupled and uncoupled growth of the stable compounds produces a regular lamellar eutectic structure and an anomalous eutectic structure, respectively. The crystallization and solid-state decomposition of the metastable Co5Si3 compound brings about a fine-grained two-phase mixture, which represents another type of anomalous eutectic structure. The results provide proof of two rare mechanisms of anomalous eutectic formation and shed light onto metastable phase relations in the undercooled region of the CoSi system.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Acta Materialia - Volume 142, 1 January 2018, Pages 172-180
نویسندگان
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