کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5435818 | 1509537 | 2017 | 10 صفحه PDF | دانلود رایگان |
Phase evolution of dilute, highly immiscible, Cu alloys (Cu-Nb, Cu-V, and Cu-Ta) during low-temperature severe plastic deformation was investigated using large-scale molecular dynamics simulations. At low solute concentrations, each system maintained a FCC structure in steady state, but as the concentration was increased above a saturation limit (0.3Â at.% for Ta, 1Â at.% for Nb and 5Â at.% for V), the system became two-phase, comprising co-existing FCC and amorphous phases. Unlike Cu-Nb and Cu-V, the amorphous phase in the Cu-Ta system showed strong solute partitioning. Increasing the solute concentration above a second phase boundary (8Â at.% V, 9Â at.% Nb, and 24Â at.% Ta) led to complete amorphization. Throughout the two-phase region, the compositions of the FCC and amorphous phases remained nearly constant, thus following the lever rule. Initiating the systems either as a FCC homogeneous alloy, or with a BCC sphere embedded in a Cu matrix, had no effect on the steady state microstructure, implying uniqueness of the steady state under low-temperature shear deformation. Lastly, chemical order and phase partitioning in the amorphous Cu-Ta system under low-temperature shear is found remarkably similar to that in the equilibrium structure above the melting temperature.
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Journal: Acta Materialia - Volume 139, 15 October 2017, Pages 205-214