کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5436503 | 1509554 | 2017 | 12 صفحه PDF | دانلود رایگان |
The atomic arrangement and microsegregation in the vicinity of thermally induced antiphase boundaries in a Ni50Mn20In30 Heusler alloy are investigated through multislice simulations, high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), X-ray diffraction pattern Rietveld analysis, energy-dispersive X-ray spectroscopy, and modified Bragg-Williams-Gorsky calculations. Intensity analysis of atomic-resolution HAADF-STEM images revealed that a 180° geometrical phase shift occurred across the antiphase boundaries, accompanied by a decay in the degree of atomic order and an enrichment of In. Energy-dispersive (X-ray) spectroscopy analysis revealed an In enrichment as high as 2.7 at.% at the center of the antiphase boundaries, comparable to that (1.0-1.8 at.%) suggested by the parallel tangent law for the Gibbs energy curves of the L21 and B2 phases using the modified Bragg-Williams-Gorsky calculation. This suggests that microsegregation occurs at the antiphase boundaries and can be understood basically within the framework of the local thermodynamic equilibrium.
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Journal: Acta Materialia - Volume 122, 1 January 2017, Pages 166-177