کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
63660 1419873 2016 7 صفحه PDF سفارش دهید دانلود کنید
عنوان انگلیسی مقاله ISI
In-situ hydrothermal synthesized γ-Al2O3/O-g-C3N4 heterojunctions with enhanced visible-light photocatalytic activity in water splitting for hydrogen
ترجمه فارسی عنوان
پیوند ناهمگون γ-Al2O3/O-g-C3N4 سنتز شده با هیدروترمال در محل با فعالیت فوتوکاتالیستی نور مرئی افزایشی در تقسیم آب برای هیدروژن
کلمات کلیدی
G-C3N4 آلاییده شده با O ؛ گاما-Al2O3 ؛ فوتوکاتالیست نور مریی؛ هیدروترمال در محل ؛ هیدروژن
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی

In this work, γ-Al2O3 and hydrogen peroxide treated g-C3N4 (O-g-C3N4) were combined through a novel in-situ hydrothermal method to form heterojunction structured photocatalysts. These photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), UV–vis diffuse reflectance spectroscopy and photoluminescence spectroscopy (PL). FT-IR results indicate that oxygen functional groups can be grafted on the surface of O-g-C3N4 by hydrogen peroxide treatment. The visible light photocatalytic hydrogen evolution rate was investigated in 10 vol% TEOA aqueous solution. The optimal Al2O3 mass content is set to be 20 wt% and the corresponding hydrogen evolution rate is 1288 µmol/h/g which is approximately 6, 3 folds that of pristine g-C3N4 and O-g-C3N4 respectively and 1.6 folds that of mechanical mixed composite with the same Al2O3 mass content. The photocurrent density–time curves were carried out under visible light illumination for four on–off cycles. The electrochemical impedance spectroscopy (EIS) measurements verified the enhanced separation efficiency of electron–hole pairs. This work raised a new method to form the heterojunction structured photocatalysts and achieved a remarkable improvement of the photocatalytic activity in water splitting for hydrogen under visible light irradiation.

Different mass ratios of γ-Al2O3/O-g-C3N4 heteojunctions are prepared through a novel one step hydrothermal method and the photocatalytic activity of the heterojunctions under visible light irradiation is significantly enhanced.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Energy Chemistry - Volume 25, Issue 4, July 2016, Pages 594–600
نویسندگان
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