کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6631138 | 1424940 | 2018 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Monitoring free radicals formation in the biodiesel oxidation reaction via electronic paramagnetic resonance
ترجمه فارسی عنوان
نظارت بر ایجاد رادیکال های آزاد در واکنش اکسیداسیون بیودیزل از طریق رزونانس پارامغناطیس الکترونیکی
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Biodiesel is an environmentally friendly alternative for petro-diesel. However, its degradation caused by radical oxidative reactions generates free radicals that damage the mechanics of vehicles. Spin trapping is a powerful resource for quantifying the short-lived and unstable free radicals liberated in these reactions. In this work, the formation of free radicals in samples of corn, soybean, and commercial biodiesel was investigated via electron paramagnetic resonance (EPR) using the spin trapping technique. The samples were incubated using the spin trap α-Phenyl-N-tert-butylnitrone (PBN) and analyzed via X-band EPR at room temperature and under heating at 70â¯Â°C. The experimental and simulated absorption spectra of the entrapped radicals allowed both identifying the presence of a derivative of the hydroxyl radical and characterizing the degradation stages of biodiesel. This result was discussed and compared with the accelerated heating method. The analysis allowed to establish EPR as a suitable, quick, and inexpensive way of probing the degradation of biodiesel in comparison with standard methods.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 224, 15 July 2018, Pages 255-260
Journal: Fuel - Volume 224, 15 July 2018, Pages 255-260
نویسندگان
Ana Carolina Gomes Mantovani, LetÃcia ThaÃs Chendynski, Aroldo Salviato, DionÃsio Borsato, Vinicius Tadeu Santana, Eduardo Di Mauro,