کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7043397 | 1456911 | 2019 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mixed matrix membranes incorporated with three-dimensionally ordered mesopore imprinted (3DOm-i) zeolite
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کلمات کلیدی
FFTSAXSSAXDtetraethyl orthosilicateN-methyl-2-pyrrolidone3DOMaminopropyltriethoxysilaneNMPLMWPPNASDATEOSHMAp-nitroanilineMOFSACAminopropyltrimethoxysilane - آمینوپروپیلل تریموتوکسیلانSteam-assisted crystallization - بلورسازی کمک بخارMixed matrix membrane - غشا شبکه آمیخته، غشاهای ماتریس مخلوطMmm - مامانAPTES - مناسبStructure directing agent - نماینده ساختار سازمانیX-ray diffraction - پراش اشعه ایکسXRD - پراش اشعه ایکسSmall-angle X-ray diffraction - پراش اشعه ایکس با زاویه کوچکSmall-angle X-ray scattering - پراکندگی اشعه ایکس با زاویه کوچکMetal organic framework - چارچوب آلی فلزی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
MFI and LTA zeolites were synthesized inside three-dimensionally ordered mesoporous (3DOm) carbon. After the removal of the carbon, a highly crystalline 3DOm-imprinted zeolite with tunable and ordered mesopores was obtained. The nominal mesopore size can be finely controlled from 5 to 15â¯nm by changing the cage size of the 3DOm carbon. Under different synthesis conditions, the crystal size of the 3DOm-imprinted (3DOm-i) MFI was tuned from approximately 100â¯nm to several micrometers. The 3DOm-i zeolite was mesoporous and exhibited a spherical shape with a rough external surface. With the synthesis of 3DOm-i zeolites, mixed matrix membranes (MMMs) were prepared by incorporating them into a commercial polyimide matrix (i.e., Matrimid® 5218). Both MFI- and LTA-containing MMMs exhibited good adhesion between the zeolites and polymer because of their imprinted mesopore structure and rough external surface. Also, both MMMs exhibited a substantial increase in permeability to all the gas penetrants used in this work (except for NF3), resulting in an excellent N2/NF3 separation efficiency.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 210, 8 February 2019, Pages 29-37
Journal: Separation and Purification Technology - Volume 210, 8 February 2019, Pages 29-37
نویسندگان
Pyung Soo Lee, Do-Young Hong, Ga-Young Cha, Heseong An, Su-Young Moon, Munsuk Seong, Bong-Jun Chang, Jong Suk Lee, Jeong-Hoon Kim,