کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7214466 | 1469465 | 2018 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Compact, flexible conducting polymer/graphene nanocomposites for supercapacitors of high volumetric energy density
ترجمه فارسی عنوان
نانو کامپوزیت های پلیمری / انعطاف پذیر هدایت انعطاف پذیر برای ابررساناها با تراکم انرژی حجمی بالا
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کلمات کلیدی
گرافن، انجام پلیمرها، ظرفیت خازنی،
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
چکیده انگلیسی
Graphene is extensively utilized in energy storage devices because of its high surface area and electronic conductivity as well as ease of electrode fabrication. But graphene sheets often stack themselves in polymeric matrices leading to poor capacitive performance. This problem was addressed herein by developing and inserting respectively two types of nano-sized conducting polymers into graphene interlayer spacing. The resulting hydrogel composite electrodes demonstrated efficient electron transfer for fast and reversible Faradaic reactions at the interface. Theoretical modelling by the density functional theory suggested that the reduction involve 2H+ transfer steps from polyaniline to graphene oxide: the first step would be an epoxy-ring opening process after activation of the C-O bond, and the second step would be C-O rupture leading to a de-epoxidation process. This binder-free electrode demonstrated high cycling performance and ultrahigh volumetric capacitance of 612â¯Fâ¯cmâ3, being 10 times higher than the activated carbon used in the current industry. The study represents a step forward towards the fabrication of flexible, high-energy density supercapacitors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 160, 26 May 2018, Pages 50-59
Journal: Composites Science and Technology - Volume 160, 26 May 2018, Pages 50-59
نویسندگان
Mahmoud Moussa, Maher F. El-Kady, Safwat Abdel-Azeim, Richard B. Kaner, Peter Majewski, Jun Ma,