کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8145029 | 1524066 | 2018 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Physical, optical and radiative properties of CaSO4-B2O3-P2O5 glasses doped with Sm3+ ions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
فیزیک و نجوم
فیزیک اتمی و مولکولی و اپتیک
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چکیده انگلیسی
Trivalent rare earth ions doped borosulfophosphate glasses are in high demand owing to their several unique attributes that are advantageous for applications in diverse photonic devices. Thus, Sm3+ ion doped calcium sulfoborophosphate glasses with composition of 25CaSO4-30B2O3-(45âx)P2O5-xSm2O3 (where xâ¯=â¯0.1, 0.3, 0.5, 0.7 and 1.0 mol%) were synthesized using melt-quenching technique. X-ray diffraction confirmed the amorphous nature of the prepared glass samples. Differential thermal analyses show transition peaks for melting temperature, glass transition and crystallization temperature. The glass stability is found in the range 91â¯Â°C to 116â¯Â°C which shows increased stability with addition of Sm2O3 concentration. The Fourier transform infrared spectral measurements carried out showed the presence of vibration bands due to PO linkage, BO3, BO4, PO4, POP, OPO, SOB, and BOB unit. Glass density showed increase in value from 2.179 to 2.251â¯g cmâ3 with increase in Sm2O3 concentration. The direct, indirect band gap and Urbach energy calculated were found to be within 4.368-4.184â¯eV, 3.641-3.488â¯eV and 0.323-0.282â¯eV energy ranges, respectively. The absorption spectra revealed ten prominent peaks centered at 365, 400, 471, 941, 1075, 1228, 1375, 1477, 1528 and 1597â¯nm corresponding to 4D3/2,6H5/2â4I11/2,6P3/2, 6F11/2, 6F9/2, 6F7/2, 6F5/2, 6F3/2, 6H15/2 and 6F1/2 transitions respectively. Photoluminescence spectra monitored at the excitation of 398â¯nm exhibits four emission bands positioned at 559, 596,643 and 709â¯nm corresponding to 4G5/2â6H5/2, 6H7/2, 6H9/2 and 6H11/2 transitions respectively. The nephelauxetic parameters calculated showed good influence on the local environment within the samarium ions site and the state of the SmO bond. The Judd-Ofelt intensity parameters calculated for all glass samples revealed that Ω6â¯>â¯Î©4â¯>â¯Î©2. The emission cross-section and the branching ratios values obtained for 4G5/2â6H7/2 transition indicate its suitability for LEDs and solid-state laser application.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Physics - Volume 56, Issue 3, June 2018, Pages 932-943
Journal: Chinese Journal of Physics - Volume 56, Issue 3, June 2018, Pages 932-943
نویسندگان
Y.A. Yamusa, Rosli Hussin, W.N. Wan Shamsuri,