کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9575154 | 1504340 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrical resistivity of monolayers and bilayers of alkanethiols in tunnel junction with gate electrode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrical resistivity of monolayers and bilayers of alkanethiols in tunnel junction with gate electrode Electrical resistivity of monolayers and bilayers of alkanethiols in tunnel junction with gate electrode](/preview/png/9575154.png)
چکیده انگلیسی
The tunneling resistances of monolayers and bilayers of n-alkanethiols in macroscopic Hg-Hg junctions with an electrochemical gate are reported. The resistances near zero bias calculated per 1 hydrocarbon chain vary from (5 ± 4) Ã 1012 Ω for n-nonanethiol to (4 ± 2) Ã 1016 Ω for n-octadecanethiol. These values indicate that monolayers of hydrocarbons in Hg-Hg junctions are substantially more resistive as compared to measurements employing microscopic tunnel junctions. The tunneling resistances of monolayer junctions are approximately 1 order of magnitude larger than those of bilayer junctions containing the same number of atoms indicating inefficient electronic coupling across the non-bonded -CH3|Hg interface. The symmetric current-voltage curves observed for the asymmetric junctions of Hg-S-(CH2)n-CH3|Hg type suggest that these junctions do not behave as molecular diodes. Additional experimental evidence for the nature of the -CH3|Hg interface in the Hg-S-(CH2)n-CH3|Hg junction is also presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 319, Issues 1â3, 7 December 2005, Pages 235-242
Journal: Chemical Physics - Volume 319, Issues 1â3, 7 December 2005, Pages 235-242
نویسندگان
Roger L. York, David Nacionales, Krzysztof Slowinski,