کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9577921 | 1505200 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Glass transition temperature of a cationic polymethacrylate dependent on the plasticizer content - Simulation vs. experiment
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Atomistic molecular dynamics simulations (NPT ensemble) are performed to compute the specific volume as a function of temperature of cationic polymethacrylate (Eudragit® RS) with varying plasticizer (triethylcitrate) content ranging from pure polymer to a plasticizer weight proportion of 7.70%. The simulated glass transition temperature of these polymer-plasticizer blends is determined as the temperature marking the kink in the slope of specific volume vs. temperature plots. A linear dependence of the glass transition temperature on the plasticizer content is found. The computational findings are supported by differential scanning calorimetry experiments showing the same trend thus validating the applied computational method.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics Letters - Volume 406, Issues 1â3, 23 April 2005, Pages 90-94
Journal: Chemical Physics Letters - Volume 406, Issues 1â3, 23 April 2005, Pages 90-94
نویسندگان
Karl G. Wagner, Martin Maus, Andreas Kornherr, Gerhard Zifferer,