کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9594520 | 1507964 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Evidence for emission and transfer of energy from excited edge sites of MgO smokes by photoluminescence experiments
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
New features are observed in photoluminescence spectra of MgO smokes produced in controlled conditions, an experiment inspired by previous measurements on cleaved MgO(1Â 0Â 0). Upon photoexcitation at 5.17-5.45Â eV, most luminescence spectra observed can be decomposed into two bands, peaking at 3.82-3.86Â eV (the highest energy ever recorded in such experiment) and 3.20Â eV, respectively. It is assumed that the 3.82-3.86Â eV band is related to the luminescence at four-coordinated (4C) defect-free edge sites and that the 3.20Â eV band arises from the excitation transfer from 4C edge sites towards less-coordinated 3C sites. A minor contribution to the 3.20Â eV band observed upon excitation with 4.6Â eV photons is assigned to a direct excitation of 3C sites. Within these assumptions, water chemisorption-desorption is suggested to produce less-coordinated sites (the 3.20Â eV band increases in intensity) at the expense of 4C sites (the 3.84Â eV band decreases). The huge sensitivity of the 3.84Â eV/3.20Â eV branching ratio to the formation of defects on 4C edges is suggested to explain the lack of consensus about the photoluminescence of MgO.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 595, Issues 1â3, 5 December 2005, Pages 172-182
Journal: Surface Science - Volume 595, Issues 1â3, 5 December 2005, Pages 172-182
نویسندگان
Romain Hacquart, Jean-Marc Krafft, Guylène Costentin, Jacques Jupille,