کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1182232 1491612 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and Application of Polyimide Coated Stir Bar for Extraction of Phenols in Environmental Water Samples
ترجمه فارسی عنوان
تهیه و استفاده از نوار پیوسته پوشش پلی یید برای استخراج فنل ها در نمونه های محیطی آب
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی

A polyimide coated stir bar for sorptive extraction (SBSE) was prepared by immersion precipitation method and evaluated by using 5 phenols and chlorinated phenols as model samples. The highest extraction efficiency was achieved among all commercial extraction phases of SBSE reported. Experimental parameters including stirring speed, ionic strength, extraction temperature, extraction time, desorption temperature and time were optimized. Under the optimal conditions such as 100 mL of sample, 30% NaCl, extraction time of 30 min, stirring speed of 800 rpm and extraction temperature of 25 °C, the target compounds were recovered by thermal desorption at 300 °C for 4 min. More than two orders of magnitude of linearity were obtained (R ≥ 0.9995). LOQs (S/N = 10) were 0.028–0.123 μg L−1, and RSDs were in the range of 1.6%–9.7%. The polyimide SBSE coupled with gas chromatography-mass spectrometry was applied to the extraction and analysis of phenols in real samples, including tap water, sea water, and waste water. It was found that the polyimide SBSE showed high selectivity towards polar compounds and high thermostability up to 350 °C.

Polyimide coated stir bar for sorptive extraction (SBSE) was prepared by immersion precipitation method, and its performances were evaluated with 5 phenols as model analytes. It was found that the polyimide SBSE had high selectivity towards polar compounds and high thermostability up to 350 °C.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Analytical Chemistry - Volume 44, Issue 6, June 2016, Pages 842–849
نویسندگان
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