Effect of CeO2-ZrO2 on Pt/C electrocatalysts for alcohols oxidation

The electrocatalytic activity and stability of Pt/C catalyst modified by using CeO2-ZrO2 mixed oxides for the alcohols electrochemical oxidation as probes were investigated. The catalyst samples were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical properties were measured by a three electrode system on electrochemical workstation (IVIUM). The results showed that the presence of CeO2-ZrO2 might be associated with the presence of Pt, which indicated that possibly there was synergistic effect between CeO2-ZrO2 and Pt nanoparticles. The electrocatalytic activity and stability of Pt-MOx/C (M=Ce, Zr) for methanol and ethanol oxidation was better than that of Pt-CeO2/C, which was attributed to that CeO2-ZrO2 composited oxides enhanced oxygen mobility and promoted oxygen storage capacity (OSC). Furthermore, the best performance was found when the molar ratio of CeO2 to ZrO2 was 2:1 for the oxidation of methanol and ethanol. The forward peak current density of Pt-MOx/C (M=Ce, Zr, Ce:Zr=2:1) towards the methanol electrooxidation was about 3.8 times that of Pt-CeO2/C. Pt-MOx/C (M=Ce, Zr) appeared to be a promising and less expensive methanol oxidation anode catalyst.

Graphical AbstractCyclic voltammograms of Pt-MOx/C (M=Ce, Zr) in the solution of 0.5 mol/L H2SO4 containing 1.0 mol/L CH3OH at a scan rate of 50 mV/SFigure optionsDownload as PowerPoint slide