کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1315055 | 976000 | 2010 | 5 صفحه PDF | دانلود رایگان |
A terminal palladium (II) fluoride complex (FPNP)PdF (where FPNP is a an anionic fluoro-substituted diarylamido/bis(phosphine) pincer ligand) has been prepared and characterized spectroscopically and structurally. An X-ray diffraction study revealed an approximately square–planar environment about Pd and a short Pd–F bond distance. (FPNP)PdF reacted with silanes containing electron-withdrawing groups on Si by exchange of fluoride with one of the substituents on Si. An analysis of the 19F chemical shifts of both the Pd-bound fluoride and of the fluorines on the backbone of the FPNP ligand is provided.
A terminal palladium fluoride supported by an FPNP ligand has been synthesized and characterized. This complex possesses an approximately square–planar environment about Pd and a short Pd–F bond. It reacts with silane reagents containing electron-withdrawing groups by exchange of fluorine with a substituent on silicon.Figure optionsDownload as PowerPoint slide
Journal: Journal of Fluorine Chemistry - Volume 131, Issue 11, November 2010, Pages 1257–1261