کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5142166 1496026 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Applied electrochemical biosensor based on covalently self assembled monolayer at gold surface for determination of epinephrine in the presence of Ascorbic acid
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Applied electrochemical biosensor based on covalently self assembled monolayer at gold surface for determination of epinephrine in the presence of Ascorbic acid
چکیده انگلیسی
In this paper, a new electrochemical sensor for the determination of epinephrine (Epi) in the presence of ascorbic acid (AA) is described. The characterization of Au TMBH self-assembled monolayer modified electrode (TMBH SAM-ME) was investigated by cyclic voltammetry (CV) using the [Fe(CN)6]−3/−4 redox couple. The mediated oxidation of Epi at the modified electrode was investigated by voltammetric methods and the values of transfer coefficient (α), the ionic exchanging current density (io), catalytic rate constant (kh) and diffusion coefficient (D) were calculated. By double potential step chronoamperometric experiments (DPCHA) at the modified electrode was obtained two linear segments of 1.7-24.9 μM and 24.9-91.7 μM by a detection limit (3σ) of 0.19 ± 0.01 μM for Epi. The advantages of this modified electrode were reproducibility and repeatability, stability and anti fouling effect against oxidation products of Epi at the surface of TMBH SAM-ME. Finally, the modified electrode was shown agreeable responses to recovery of Epi from real sample solutions by standard addition method.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 10, Supplement 1, February 2017, Pages S657-S664
نویسندگان
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