کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5447631 | 1511760 | 2018 | 36 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced stability of sodium storage exhibited by carbon coated Sb2S3 hollow spheres
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
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چکیده انگلیسی
Antimony sulfide (Sb2S3) has been shown as a promising candidate for sodium ions batteries, in considering the gravimetric energy density and high theoretical capacity. Hollow-sphere Sb2S3 coated with carbon are successfully designed through Oswald ripening process. The Sb2S3/C utilized as SIBs anode displays excellent electrochemical properties, delivering a high charge capacity of 693.4Â mAh gâ1 at 0.2Â AÂ gâ1 between 0.01 and 3.0Â V (vs. Na+/Na). Its reversible capacity can keep 545.6Â mAh gâ1, with a retention of â¼80% after 100 cycles. Even the current densities return from 6.4 to 0.2Â AÂ gâ1, the Sb2S3/C still maintains 550.8Â mAh gâ1 after 70 cycles. Combining the large void space with carbon layer, the advantages are noticed when the increased electrolyte penetration area, improved electronic conductivity and shortened Na+ diffusion length are attained concurrently, resulting in the excellent specific capacity and cycling stability. The study provides an effect strategy in improving the electrochemical performances of metal sulfides as anode for SIBs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 203, 1 January 2018, Pages 185-192
Journal: Materials Chemistry and Physics - Volume 203, 1 January 2018, Pages 185-192
نویسندگان
Peng Ge, Hongshuai Hou, Xiaobo Ji, Zhaodong Huang, Simin Li, Lanping Huang,