کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5453673 | 1513991 | 2018 | 37 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
SnSe2 Quantum Dot/rGO composite as high performing lithium anode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
فناوری سوخت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
There have been limited applications in Tin Selenide based anode materials for lithium ion batteries due to low capacities from the alloying process (SnSe: 596 mAh gâ1, SnSe2: 426 mAh gâ1). This is mainly due to the significant loss of capacity during initial conversion process with the formation of Li2Se; a process that is considered irreversible in Tin based (SnXn, X = O, S, Se, n = 1 or 2) anode materials. Herein, ultra-fine Quantum Dots (QDs) of SnSe2 were designed to be embedded in a 3D matrix of rGO to release Sn nanoparticles that are able to catalyze the decomposition Li2Se and drive the conversion of Sn to SnSe2. In this manner, both conversion and alloying reactions can be utilized that greatly increases the effective capacity of SnSe2 anode. Through facile solvothermal synthesis followed by freeze-drying and thermal annealing, the rationally designed SnSe2 QDs/rGO effectively promoted reversible conversion of Sn to SnSe2. As a result, the nanocomposite exhibited enhanced capacities (778.5 mAh gâ1 at current density of 50 mA gâ1) that are beyond its theoretical values. The designed nanostructure also endowed the nanocomposite with high rate capabilities (324.5 mAh gâ1 at current density of 5000 mA gâ1) and ultra-long cycle life (92.2% capacity retention after 3000 cycles at 2000 mA gâ1). Post cycling analysis through ex situ TEM and XRD, coupled with electrochemical studies, were carried out to verify the reversible conversion reactions in SnSe2 QDs/rGO. The successful utilization of both conversion and alloying reactions in SnSe2 enables Tin Selenides to be on par with its oxide and sulfide analogues and hence a potential anode towards high energy density lithium ion batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy Storage Materials - Volume 10, January 2018, Pages 92-101
Journal: Energy Storage Materials - Volume 10, January 2018, Pages 92-101
نویسندگان
Zhi Xiang Huang, Bo Liu, Dezhi Kong, Ye Wang, Hui Ying Yang,