Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite

A series of Ca-Al hydrocalumite with different Ca/Al ratios (1–6) were synthesized and used in the transesterification of glycerol with dimethyl carbonate (DMC) to glycerol carbonate (GC) under mild conditions. The calcined Ca-Al hydrocalumites were active with a selectivity toward GC that reached 97% at 93% conversion of glycerol over the sample with Ca/Al = 2 at 70 °C, 3 h, and DMC/glycerol = 3. The glycerol conversion depended mainly on the proportion of strong basic sites in the calcined Ca-Al catalysts. The Ca12Al14O33 phase in the calcined catalysts was stable, but CaO was lost in recycle experiments and thus brought deactivation.

Graphical AbstractCalcined Ca-Al hydrocalumites are active and selective for the transesterification of glycerol with dimethyl carbonate, and the yield of glycerol carbonate reached 92% at 70 °C and 3 h.Figure optionsDownload as PowerPoint slide