کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
63713 48249 2016 17 صفحه PDF سفارش دهید دانلود کنید
عنوان انگلیسی مقاله ISI
Transformation of bio-derived acids into fuel-like alkanes via ketonic decarboxylation and hydrodeoxygenation: Design of multifunctional catalyst, kinetic and mechanistic aspects
ترجمه فارسی عنوان
تبدیل اسیدهای حاصل از زیست به آلکان های سوخت مانند از طریق دکربوکسیلاسیون ketonic و hydrodeoxygenation: طراحی جنبه های کاتالیزور، جنبشی و مکانیکی چندعاملی
کلمات کلیدی
اسیدهای کربوکسیلیک؛ کاتونیزاسیون؛ Hydrodeoxygenation؛ آلکین؛ سوخت زیستی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
چکیده انگلیسی

The combination of a low cost source of Biofine's levulinic acid with available way of valeric acid synthesis opens up new opportunities for valeric acid as a promising bio-derived source for synthesis of valuable compounds for transportation sector. The present review illustrates the development of different approaches to one–pot synthesis of fuel-like alkanes from lignocellulose derived carboxylic acids where particular focus is given to valeric acid consecutive decarboxylative coupling (ketonization) and ketone hydrodeoxygenation in a single reactor over one catalyst bed. The key factors that influence the catalytic performance on both ketonization and hydrodeoxygenation steps as well as their cross-influence will be clarified to provide insights for the design of more efficient catalysts for the one-pot transformation. Valeric acid is considered as a potential acid source from viewpoint of cost effectiveness and feasibility of such transformation with reasonable alkane yield. The both reaction mechanisms and kinetics will also be discussed to understand deeply how the selective CC coupling and following CO hydrogenation can be achieved.

Recent advances in understanding the key factors affecting the carboxylic acid ketonization and ketone hydrodeoxygenation to develop one-pot synthesis of alkanes for fuel application over multifunctional catalysts have been highlighted.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Energy Chemistry - Volume 25, Issue 2, March 2016, Pages 208–224
نویسندگان
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