کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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63791 | 48253 | 2015 | 9 صفحه PDF | دانلود رایگان |
Based on the previous research work in our laboratory, we have designed and synthesized a small-molecule, hole transport material (HTM) POZ6-2 using phenoxazine (POZ) as central unit and dicyanovinyl units as electron-withdrawing terminal groups. Through the introduction of a 2-ethyl-hexyl bulky chain into the POZ core unit, POZ6-2 exhibits good solubility in organic solvents. In addition, POZ6-2 possesses appropriate energy levels in combination with a high hole mobility and conductivity in its pristine form. Therefore, it can readily be used as a dopant-free HTM in perovskite solar cells (PSCs) and a conversion efficiency of 10.3% was obtained. The conductivity of the POZ6-2 layer can be markedly enhanced via doping in combination with typical additives, such as 4-tert-butylpyridine (TBP) and lithium bis(trifluoromethanesulfonyl) imide (LiTFSI). Correspondingly, the efficiency of the PSCs was further improved to 12.3% using doping strategies. Under the same conditions, reference devices based on the well-known HTM Spiro-OMeTAD show an efficiency of 12.8%.
Perovskite solar cell containing phenoxazine based hole transport material achieved an efficiency of 12.3%.Figure optionsDownload as PowerPoint slide
Journal: Journal of Energy Chemistry - Volume 24, Issue 6, November 2015, Pages 698–706