کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6468628 1362319 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Removal of uranium (VI) from nuclear effluents onto aluminophosphate and silicoaluminophosphate molecular sieves
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Removal of uranium (VI) from nuclear effluents onto aluminophosphate and silicoaluminophosphate molecular sieves
چکیده انگلیسی

Aluminophosphate and silicoaluminophosphate molecular sieves with both five (AFI) and eleven (AEL) type structures are synthesized by hydrothermal crystallization at 473 K, using tripropylamine and dipropylamine as a structure-directing template. The as-prepared AFI and AEL sieves are characterized and then assessed as sorbents for uranium (VI) from radioactive effluents. The sorption process is used to reduce the volumes of effluents and convert them into a stable solid waste. The batch experimental studies are carried out to evaluate the AEL and AFI structure effect on the removal of uranium. The AlPO4-5, SAPO-5, AlPO4-11 and SAPO-11 are applied to radioactive effluents with different activities obtained from Nuclear Research Center of Draria, Algeria. Important decontamination factor values are obtained for AFI sorbents. Thermodynamic parameters, namely, the enthalpy (ΔH), entropy (ΔS) and free energy (ΔG) for each sorption process are calculated. The collected results indicated that sorbents are effective materials for the removal of uranium (VI) ions, the sorbent with AFI structure being a highly effective material for the removal of uranium (VI) ions from nuclear effluents.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Comptes Rendus Chimie - Volume 20, Issue 7, July 2017, Pages 704-709
نویسندگان
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