کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7690942 | 1495964 | 2018 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Through-bond communication between polymer-bound phosphinic acid ligands and trivalent metal ions probed with FTIR spectroscopy
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The binding of trivalent metal ions to immobilized ligands is analyzed to determine the principal type of interaction, the extent of ion exchange, and changes due to through-bond communication. FTIR spectroscopy is found to be a readily accessible means of determining through-bond communication and spectra provide support for a molecular level interpretation of the interaction. The affinity of the phosphinic acid ligand for Al(III), La(III), Lu(III), Fe(III), and In(III) is quantified with distribution coefficients from 0.01-6â¯M nitric acid solutions. High affinities are evident with In(III)â¯>â¯Fe(III)â¯>â¯Lu(III)â¯>â¯La(III)â¯>â¯Al(III). The affinities correlate with the softness parameter and thus the polarizability of the metal ion. The FTIR spectrum of the phosphinic acid has two incompletely separated bands at 1168/1126â¯cmâ1 associated with the PO bond and two similar bands at 967/951â¯cmâ1 due to the PO(H) bond. The bands at 1168/951 and 1126/967â¯cmâ1 are assigned to different hydrogen bonded conformers within the metal-free polymer. Through-bond communication is evident as the extent of metal ion binding increases: the PO and PO bands at 1168 and 951â¯cmâ1, respectively, collapse into a single band between 1040 and 1080â¯cmâ1 representative of PO2(M) while hydrogen bonding among unexchanged P(O)OH ligands gives the bands at 1133 and 981â¯cmâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Vibrational Spectroscopy - Volume 95, March 2018, Pages 80-89
Journal: Vibrational Spectroscopy - Volume 95, March 2018, Pages 80-89
نویسندگان
Spiro D. Alexandratos, Xiaoping Zhu,