کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
977410 | 1480197 | 2006 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Critical behavior of thermal phase transitions of iota-carrageenan in CaCl2 solution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
ریاضیات
فیزیک ریاضی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In situ photon transmission method was applied to study thermal phase transitions of ι-carrageenan in CaCl2 solution. Coil-to-helix (c-h) and helix-to-dimer (h-d) transitions were detected upon cooling. An extra dimer-to-dimer (d-d) transition was observed as well during cooling at low-temperature region. Upon heating only dimer-to-helix (d-h) and helix-to-coil (h-c) transitions were detected. Photon transmission intensity, Itr was monitored against temperature to determine several phase transitions and transition temperatures. It was observed that the c-h transition in ι-carrageenan-CaCl2 system performs a crossover between 3D percolation to classical theory. Upon heating, the specific heat exponent over the d-h transition was extracted from the transmitted intensity data and was found to be 0.045.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 367, 15 July 2006, Pages 69-78
Journal: Physica A: Statistical Mechanics and its Applications - Volume 367, 15 July 2006, Pages 69-78
نویسندگان
Haluk Ãzbek, Ãnder Pekcan,