کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
230002 | 1427364 | 2016 | 6 صفحه PDF | دانلود رایگان |
• Solubility of CO2 was independent of the molecular weight (MW) of PC.
• Crystallinity and crystallization rate decreased with increasing MW..
• Crystallization rate was properly correlated including MW dependence.
The effect of molecular weight on the crystallinity and crystallization rate of polycarbonate (PC) in the presence of supercritical CO2 was studied at temperatures from 75 to 175 °C and at pressures up to 20 MPa. Crystallinities decreased ca. 0.05 and maximum crystallization rates decreased ca. 50% with an increase in the weight-average molecular weights of the PC from 19.2 to 29.8 kg/mol. Moreover, the maximum crystallization rates were properly correlated with the average absolute error of 30% by considering the changes in the glass transition temperature and melting temperature caused by the plasticization effect of dissolved CO2.
Figure optionsDownload as PowerPoint slide
Journal: The Journal of Supercritical Fluids - Volume 113, July 2016, Pages 144–149