کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10133660 | 1645599 | 2018 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Anthracene based surface acoustic wave sensors for picomolar detection of lead ions. Correlation between experimental results and DFT calculations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
104 MHz surface acoustic wave (SAW) sensors functionalized with new anthracene derivates were designed for the detection of lead ions (Pb2+) in liquid media. On the basis on quantum chemical calculations, three anthracene molecules have been synthetized and tested: 4-(9-anthrylmethoxy) benzyl[4-(9-anthrylmethoxy)phenyl]sulfone (BPS-AN); 9-{[4-({[4-(9 anthrylmethoxy) phenyl]sulfanyl}methyl)]methyl] anthracene (TDP-AN) and 2,2-bis(4 anthracenylmethoxy-1,1â²-biphenyl (BP-AN). Gravimetric results indicate that the affinity of BPS-AN towards Pb2+ ions is superior to that of TDP-AN and BP-AN, confirming thus the computational approach. The designed BPS-AN SAW sensor has a sensitivity of [7.2 ± 4.6]Ã108 [°/M], a limit of detection (LOD) of 22 pM, and displayed very high affinity to lead ions with an apparent dissociation constant Kd of order of (1.1 ± 2.7) à 10â10. Selectivity was investigated by both gravimetry and DFT calculation. Results indicate that the designed sensor is more sensitive to lead cations than copper and mercury ones. A tetrabutylphosphonium (TBP) lactate ionic liquid (IL) solution was used to regenerate the SAW sensor, permitting its further reuse a dozen times without degrading the BPS-AN recognition layer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 276, 10 December 2018, Pages 349-355
Journal: Sensors and Actuators B: Chemical - Volume 276, 10 December 2018, Pages 349-355
نویسندگان
G. Attia, S. Rahali, S. Teka, N. Fourati, C. Zerrouki, M. Seydou, S. Chehimi, S. Hayouni, J.-P. Mbakidi, S. Bouquillon, M. Majdoub, R. Ben Chaabane,