کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10410277 | 894328 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A hemin-based molecularly imprinted polymer (MIP) grafted onto a glassy carbon electrode as a selective sensor for 4-aminophenol amperometric
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Molecular imprinting technology is becoming a versatile tool for the preparation of tailor-made molecular recognition elements. This work investigates the performance of a hemin-modified molecularly imprinted polymer (MIP) used as an amperometric sensor for the detection of 4-aminophenol (4-APh). MIP particles were prepared by the precipitation polymerization method with hemin introduced as the catalytic center to mimic the active site of peroxidase. 4-APh was used as the template molecule, methacrylic acid (MAA) as the functional monomer, trimethylolpropane trimethacrylate (TRIM) as the cross-linker and 2,2â²-azobisisobutyronitrile (AIBN) as the initiator. The synthesized polymer particles were characterized in terms of particle size, porosity and morphology. The amperometric sensor used for 4-APh detection was prepared by modifying a glassy carbon electrode surface with the hemin-based MIP. Under optimized operational conditions, a linear response was obtained in the range of 10.0-90.0 μmol Lâ1, with a sensitivity of 5.5 nA L μmolâ1 and a detection limit of 3.0 μmol Lâ1. The sensor showed good repeatability (RSD = 2.7% for n = 7). It exhibited to be very selective for 4-APh even in the presence of structurally similar compounds (2-aminophenol, catechol, guaiachol, 2-cresol and chloroguaiachol). Recoveries in the range 93-111% were obtained using the sensor for the determinations of 4-APh in tap and river water samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 152, Issue 2, 1 March 2011, Pages 220-225
Journal: Sensors and Actuators B: Chemical - Volume 152, Issue 2, 1 March 2011, Pages 220-225
نویسندگان
José de Ribamar Martins Neto, Wilney de Jesus Rodrigues Santos, Phabyanno Rodrigues Lima, Sônia Maria Carvalho Neiva Tanaka, Auro Atsushi Tanaka, Lauro Tatsuo Kubota,