کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10410417 | 894437 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mixed-ligand nanoparticles of chlorobenzenemethanethiol and n-octanethiol as chemical sensors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of mixed-ligand gold nanoparticles were synthesized, characterized and used to form transducer films to investigate and enhance vapor-sensing properties. Chlorobenzenemethanethiol (CBMT) nanoparticle, prepared using a two-phase method, was used for place-exchange reactions with a varying amount of n-octanethiol (OT) to produce a series of mixed-ligand gold nanoparticles (Au_CBMT-OT-1, Au_CBMT-OT-2, and Au_CBMT-OT-3). The nanoclusters were characterized by 1H NMR spectroscopy, thermal gravimetric analysis (TGA), and transmission electron microscopy (TEM). Thin film transducers of the monolayer-protected nanoparticles were formed through a dip-coating procedure on glass substrates mounted with interdigitated gold electrodes. SEM analysis indicated that mostly the surfaces of the sensors films were smooth. Nanoparticle sensors experienced repeated cycles of analyte vapors and blank air gas as the analyte concentrations were varied. Mostly the nanoparticle sensors produced rapid and reversible responses toward the vapors of 1-propanol, acetone and cyclohexane. Linear relationship between maximum resistance changes and vapor concentrations were observed. Above all the variations in compositions of the ligand molecules (CBMT and OT) resulted in differences in signal amplitudes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 106, Issue 1, 29 April 2005, Pages 189-198
Journal: Sensors and Actuators B: Chemical - Volume 106, Issue 1, 29 April 2005, Pages 189-198
نویسندگان
Young Jun Kim, Yoon Seok Yang, Seung-Chul Ha, Seong M. Cho, Yong Shin Kim, Hye Yoon Kim, Haesik Yang, Youn Tae Kim,