کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10410919 | 894532 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Piezoelectric quartz sensor for caffeine based on molecularly imprinted polymethacrylic acid
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Piezoelectric quartz sensor for caffeine based on molecularly imprinted polymethacrylic acid Piezoelectric quartz sensor for caffeine based on molecularly imprinted polymethacrylic acid](/preview/png/10410919.png)
چکیده انگلیسی
The feasibility of a piezoelectric quartz caffeine sensor based on a molecularly imprinted poly methacrylic acid is described. The caffeine sensor was devised by depositing the polymer onto one side of an AT-cut quartz crystal through an electropolymerization process The sensor response exhibited a linear relationship between frequency shift and the logarithm of the caffeine concentration in the range of 1Â ÃÂ 10â9 up to 1Â mg/mL. The sensor showed a sensitivity of about 53Â Hz/ln (conc., mg/mL) and a limit of detection of 5.9Â ÃÂ 10â11Â mg/mL. The performance of the sensor was affected by parameters such as the nature of the immobilizing agents, the polymer load, the thickness of the coating and the pH. Surface analysis techniques such as scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS) were performed on the sensor surface to establish the imprinting of the caffeine molecule. The SEM micrographs, AFM image and XPS spectra provided evidences for the imprinting process and the recognition of caffeine by the MIP during the sensing process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 107, Issue 2, 29 June 2005, Pages 782-790
Journal: Sensors and Actuators B: Chemical - Volume 107, Issue 2, 29 June 2005, Pages 782-790
نویسندگان
Benilda S. Ebarvia, Fortunato III,