کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10410981 | 894535 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
V2O5 nanofibres: novel gas sensors with extremely high sensitivity and selectivity to amines
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Chemiresistor-type gas sensors were fabricated by depositing vanadium pentoxide (V2O5) nanofibres from aqueous suspension onto silicon substrates. Electrical contact was made through gold electrodes. Due to the sufficiently high conductivity of the fibres, the sensors could be operated at room temperature. Extremely high sensitivity was measured for 1-butylamine (limit of detection (LOD) below 30Â ppb) and moderate sensitivity for ammonia. In contrast, only very little sensitivity was observed for toluene and 1-propanol vapours. The sensitivity to 1-butylamine increased linearly when increasing the relative humidity (rh) of the carrier gas from 0 to 60%. Contacting the fibres with either top or bottom electrodes dramatically changed the response characteristics. Based on these results, the sensing mechanism is discussed in terms of intercalation of the amine into the layered structure of the nanofibres and sorption at the nanofibre/electrode interface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 106, Issue 2, 13 May 2005, Pages 730-735
Journal: Sensors and Actuators B: Chemical - Volume 106, Issue 2, 13 May 2005, Pages 730-735
نویسندگان
Isabelle Raible, Marko Burghard, Ulrich Schlecht, Akio Yasuda, Tobias Vossmeyer,