کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10565747 971963 2015 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid phase extraction method for the study of black carbon cycling in dissolved organic carbon using radiocarbon
ترجمه فارسی عنوان
روش استخراج فاز جامد برای مطالعه چرخه کربن سیاه در کربن آلی محلول با استفاده از رادیو کربن
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
چکیده انگلیسی
Radiocarbon analysis is a powerful tool for understanding the cycling of individual components within carbon pools, such as black carbon (BC) in dissolved organic carbon (DOC). Radiocarbon (Δ14C) measurements of BC in DOC provide insight into one source of aged, recalcitrant DOC. We report a modified solid phase extraction (SPE) method to concentrate 43 ± 6% of DOC (SPE-DOC) from seawater. We used the Benzene Polycarboxylic Acid (BPCA) method to isolate BC from SPE-DOC (SPE-BC) for subsequent 14C analysis. We report SPE-BC Δ14C values, SPE-BC concentrations, and the relative BPCA distributions from Milli-Q water process blanks, two riverine reference standards, as well as a coastal and an open ocean surface water sample. The composition of BC is less aromatic in the ocean samples than those in the river standards. We find higher BC Δ14C values in the river standards (+ 148 to − 462‰) than BC in the ocean samples (− 592 to − 712‰), suggesting that BC ages within oceanic DOC. We report that BC is 4.2 ± 1.0% of SPE-DOC in the open ocean surface sample, or 1.4 ± 0.1 μM C. This work provides the methodological basis by which global BC concentrations, compositions (e.g. relative abundances of BPCA marker compounds) and ∆14C values can be assessed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Marine Chemistry - Volume 177, Part 5, 20 December 2015, Pages 697-705
نویسندگان
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