کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10569789 974730 2005 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Copper-catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one: Synthesis, structure and spectral properties of [Cu(idpa)(N-baa)]ClO4, [idpa = 3,3′-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid]
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Copper-catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one: Synthesis, structure and spectral properties of [Cu(idpa)(N-baa)]ClO4, [idpa = 3,3′-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid]
چکیده انگلیسی
The molecular structure of [Cu(idpa)(N-baa)]ClO4 (idpa = 3,3′-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid) was fully determined by IR, UV-vis, and X-ray crystal analysis. The oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one (QuinH2) using [Cu(idpa)(N-baa)]ClO4 as a catalyst results in the oxidative cleavage of the heterocyclic ring to give a N-benzoylanthranilic acid and CO as a mimic of quercetinase and 3-hydroxy-1,4-dihydroquinolin-4-one 2,4-dioxygenase action.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 8, Issue 9, September 2005, Pages 813-816
نویسندگان
, , , , , ,