کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10569789 | 974730 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Copper-catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one: Synthesis, structure and spectral properties of [Cu(idpa)(N-baa)]ClO4, [idpa = 3,3â²-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid]
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Copper-catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one: Synthesis, structure and spectral properties of [Cu(idpa)(N-baa)]ClO4, [idpa = 3,3â²-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid] Copper-catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one: Synthesis, structure and spectral properties of [Cu(idpa)(N-baa)]ClO4, [idpa = 3,3â²-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid]](/preview/png/10569789.png)
چکیده انگلیسی
The molecular structure of [Cu(idpa)(N-baa)]ClO4 (idpa = 3,3â²-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid) was fully determined by IR, UV-vis, and X-ray crystal analysis. The oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one (QuinH2) using [Cu(idpa)(N-baa)]ClO4 as a catalyst results in the oxidative cleavage of the heterocyclic ring to give a N-benzoylanthranilic acid and CO as a mimic of quercetinase and 3-hydroxy-1,4-dihydroquinolin-4-one 2,4-dioxygenase action.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 8, Issue 9, September 2005, Pages 813-816
Journal: Inorganic Chemistry Communications - Volume 8, Issue 9, September 2005, Pages 813-816
نویسندگان
József Kaizer, Tamás Csay, Miklós Czaun, Gábor Speier, Marius Réglier, Michel Giorgi,