کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10570516 974885 2005 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electron transfer reaction of Cu(II) porphyrin complex: Effect of structural deformation on the electron self-exchange rate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Electron transfer reaction of Cu(II) porphyrin complex: Effect of structural deformation on the electron self-exchange rate
چکیده انگلیسی
Oxidation reaction of the sterically constrained nonplanar Cu(II) 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin complex ([Cu(OETPP)]) by Cu2+ was investigated in acetonitrile, and a slow electron self-exchange rate of the [Cu(OETPP)]+/0 couple as compared with the planar Cu(II) porphyrin complexes was ascribed to the significant deformation of the complex accompanied with the ligand oxidation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 8, Issue 11, November 2005, Pages 979-982
نویسندگان
, , , ,