کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11016364 | 1777900 | 2019 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly selective and stable mixed-potential type gas sensor based on stabilized zirconia and Cd2V2O7 sensing electrode for NH3 detection
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, the highly selective and stable mixed potential type stabilized zirconia (YSZ) based gas sensor using Cd2V2O7 sensing electrode (SE) synthesized via simple coprecipitation method was fabricated and developed for effective detection of NH3 at 650â°C. The as-prepared Cd2V2O7 sensing material was characterized by X-ray diffraction (XRD), Raman spectrum, X-ray photoelectron spectroscopy (XPS) and Field-emission scanning electron microscopy (FESEM). The results of gas sensing measurement indicated that the sensor attached with Cd2V2O7- SE displayed the response value of â68âmV and rapid response rate of 5âs to 100âppm NH3 at 650â°C. The present device also exhibited the low detection limit of 1âppm and the piecewise sensitivities of â6 and â66âmV/decade to NH3 in the concentration ranges of 1-10âppm and 10-200âppm, respectively. Moreover, the fabricated sensor showed good reproducibility, excellent selectivity, stability to oxygen concentration, relative humidity and 30 days continuous aging of high temperature at 650â°C. And the complex impedance and polarization curves were performed to explain the selectivity and verify the sensing mechanism involving mixed potential model.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sensors and Actuators B: Chemical - Volume 279, 15 January 2019, Pages 213-222
Journal: Sensors and Actuators B: Chemical - Volume 279, 15 January 2019, Pages 213-222
نویسندگان
Fangmeng Liu, Siqi Li, Junming He, Jing Wang, Rui You, Zijie Yang, Lianjing Zhao, Peng Sun, Xu Yan, Xishuang Liang, Xiaohong Chuai, Geyu Lu,