کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
11425369 | 1489001 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Overcharge durability of Li4Ti5O12 based lithium-ion batteries at low temperature
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
The decrease in capacity at low temperature limits further application of lithium-ion batteries. This paper introduces an approach to compensating the capacity loss of Li4Ti5O12 (LTO) based lithium-ion batteries at low temperature by increasing the charging cut-off voltage. The impact of this approach on battery durability is examined afterwards, and a “tipping point” voltage for degradation is observed. Cut-off voltages over the tipping point (3.2â¯V) cause severe degradation, while those beneath the tipping point do not. The degradation mechanisms are studied with incremental capacity (IC) curve analysis, a prognostic and mechanistic (P&M) model and Scanning Electron Microscope/X-Ray Energy Dispersive Spectrometer (SEM/EDS) tests. Analysis show that the potential of the LTO anode first drops below 1â¯V when the battery is overcharged to 3.2â¯V. The electrolyte exceeds the reduction potential and decomposes on the LTO surface, forming Solid Electrolyte Interface (SEI) film with gas generation. The anode potential then gradually rises to above 1â¯V as we continue to charge the battery. However, the cathode potential exceeds 4.6â¯V, resulting in electrolyte oxidation and active material loss in the cathode. Overall, enhancing the cut-off voltage from 2.7â¯V to 3.2â¯V is effective to enlarge the charging capacity (9.5%) of the LTO batteries at â20â with slight degradation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Energy Storage - Volume 19, October 2018, Pages 302-310
Journal: Journal of Energy Storage - Volume 19, October 2018, Pages 302-310
نویسندگان
Yu Wang, Zhengyu Chu, Xuning Feng, Xuebing Han, Languang Lu, Jianqiu Li, Minggao Ouyang,