کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1192121 1492253 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Investigation on addition and abstraction channels in Cl reactions with 1-butene and isobutene
ترجمه فارسی عنوان
بررسی کانال های انتزاعی و انتزاعی در واکنش های کل با 1-بوتن و ایزوتوان
کلمات کلیدی
کانالهای اضافی و انتزاعی، واکنش های کل با 1-بوتن و ایزوتوئن، کلروبوتیل، رادیکال ها
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی


• Addition product C4H7Cl is observed as well as abstraction products C4H7 and C4H6.
• Possible addition and abstraction channels are performed at MP2/aug-cc-pvtz level.
• C4H7Cl is established via Cl reaction with the forming chlorobutyl compounds.

The reactions of the Cl radical with 1-butene and isobutene have been studied in a flow tube by utilizing photoionization mass spectrometry at the energy range of 9–11 eV. The addition C4H7Cl and abstraction C4H7 and C4H6 products were observed in the mass spectra. The experimental ionization energies for C4H7Cl from 1-butene and isobutene were determined to be 9.58 ± 0.10 and 9.56 ± 0.10 eV, respectively, consistent with ionization energies of the likely isomers at the MP2/aug-cc-pvtz level. In addition, possible addition and abstraction channels were performed at the MP2/aug-cc-pvtz level. Two addition channels for 1-butene and one for isobutene proceeded via the addition of Cl to the unsaturated bond of the butenes and then led to the chlorobutyl radicals. One abstraction channel for 1-butene and isobutene was identified to be viable, respectively. The observed addition products were established via the secondary reactions of Cl with the forming chlorobutyl compounds.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 375, 1 January 2015, Pages 1–8
نویسندگان
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