کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1192366 1492242 2015 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Strong Selectivity in Symmetry forbidden vibronic transitions in Deep Core Ionic Photofragmentation of the SF6 molecule
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Strong Selectivity in Symmetry forbidden vibronic transitions in Deep Core Ionic Photofragmentation of the SF6 molecule
چکیده انگلیسی


• Photoionization of SF6 have been studied with X-ray photons around the S K edge.
• The 1a1g → 6a1g transition plays a relevant role in the fragmentation pattern.
• The F+ ion is the most abundant species observed in the energy range studied.
• The intensity the dipole-forbidden (1a1g → 6a1g) was calculated.

Deep core photoionization of the sulfur hexafluoride molecule have been studied with X-ray photons at energies around the S K edge (from 2472 eV to 2489 eV), using time-of-flight multicoincidence technique with synchrotron radiation. Total and partial photoion yields for the fragments have been recorded as a function of the incident photon energy. The atomic fluorine ion, F+ is the most abundant species observed in the mass spectra at the energy range studied. The SF6 molecule undergoes a complete break up with the formation of atomic doubly and triply charged S2+, S3+, and F2+ fragments. The intensity of absorption for the dipole-forbidden but vibronically allowed transition S K (1a1g → 6a1g) was calculated and it is shown that it play a relevant role in the fragmentation pattern.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 388, 15 September 2015, Pages 9–16
نویسندگان
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