کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1192466 | 1492351 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Negative ions in non-polar liquids
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
The structure and mobility of positive and negative ions in non-polar liquids are analyzed. The possibility of clusters and bubbles creation around ions of both signs is discussed. It is demonstrated that complexes formed around negative metal and halogen ions in superfluid helium have qualitatively different structures, although the measured values of the mobility were similar. In the case of Baâand Gaâ ions, which have low electron affinities, a bubble is formed around the ion; this bubble is similar to an electron bubble. In the case of Clâ, Fâ, and Iâ ions, which have high electron affinities, a cluster is formed near the ion; this cluster is similar to the well-studied cluster at the He+ ion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 277, Issues 1â3, 1 November 2008, Pages 236-239
Journal: International Journal of Mass Spectrometry - Volume 277, Issues 1â3, 1 November 2008, Pages 236-239
نویسندگان
A.G. Khrapak, W.F. Schmidt,