کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1193240 1492266 2014 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Rapid characterization of chemical constituents in Saniculiphyllum guangxiense by ultra fast liquid chromatography with diode array detection and electrospray ionization tandem mass spectrometry
چکیده انگلیسی


• The first time LC–DAD/MSn investigation on S. guangxiense led to the identification of 50 compounds.
• Cyanogenic glycosides, triterpenoids, phenolic sulfates and organic acids are the main constituents.
• This paper is valuable for understanding the chemical profiles and taxonomic position of S. guangxiense.

Saniculiphyllum guangxiense as a highly distinctive species within Saxifragaceae is fallen to the critically endangered category, whose chemical and taxonomic information is still little-known. The first time LC–DAD/MSn investigation on S. guangxiense led to the detection and characterization of 50 compounds, involving cyanogenic glycosides, phenolic sulfates, triterpenoids, amino acids, phenylpropanoids, aromatic derivatives, lignans, flavonoids, nucleosides, fatty acids and carbohydrate, based on their fragmentation characteristics, UV spectra or comparison with the reference compounds. The collision induced dissociation (CID) fragmentation patterns for several types of compounds were also concluded. The main constituents of S. guangxiense were revealed as cyanogenic glycosides, triterpenoids, phenolic sulfates and organic acids, which were very different from other Saxifragaceae plants. This paper will provide valuable information for understanding its chemical profiles and taxonomic position in Saxifragaceae from a chemotaxonomic point of view.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 361, 15 March 2014, Pages 9–22
نویسندگان
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