کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1228584 | 968479 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Factorial design for optimising chromium determination in tanning wastewater
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Factorial design for optimising chromium determination in tanning wastewater Factorial design for optimising chromium determination in tanning wastewater](/preview/png/1228584.png)
چکیده انگلیسی
A totally automatized procedure for determining chromium by sequential injection analysis (SIA) linked to multivariate curve resolution with alternating least squares (MCR-ALS) is proposed. With this system Cr(III) is oxidised to chromate (Cr(VI)) and this form is then converted to dichromate in order to obtain second order data. The experimental design method was used to establish the best conditions. The identification of the most influential factors was validated using ANOVA tests. We used this method to successfully analyse total chromium in several aqueous tannery samples from various steps of a tanning process. The results from this method and those from the atomic absorbance spectroscopy (AAS) method are comparable. Sample frequency was 30 samples hâ 1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 83, Issue 2, July 2006, Pages 98-104
Journal: Microchemical Journal - Volume 83, Issue 2, July 2006, Pages 98-104
نویسندگان
V. Gómez, A. Pasamontes, M.P. Callao,