کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1250794 1496055 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Theoretical study of the reactivity of (CH3)2AlCH2I promoted cyclopropanation reactions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Theoretical study of the reactivity of (CH3)2AlCH2I promoted cyclopropanation reactions
چکیده انگلیسی

Density functional theory calculations are reported for the cyclopropanation reactions of (CH3)2AlCH2I with ethylene for two reaction channels: methylene transfer and carbometalation. These computational results suggest that the methylene transfer process is favored and the competition from the carbometalation pathway is negligible.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 4, Issue 4, October 2011, Pages 379–382
نویسندگان
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