کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1251289 | 970900 | 2007 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of Coordination Polymers Using Different Maleic Acid Ligands under Hydrothermal Conditions
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
A novel coordination polymer, [Ni(mal) (1,10â²-phen) (H2O)]n (1) (mal = malate, 1,10â²-phen = 1,10-phenanthroline) was synthesized using malic acid which was generated from maleic acid via hydrothermal reaction. Complex 1, which displays a two-dimensional supramolecular network, was formed by the addition reaction of Ni and maleic acid with water molecules. To our knowledge, several coordination polymers have been directly synthesized from malic acid, but these types of complexes have seldom been synthesized from maleic acid via hydrothermal reactions. When Ni (II) ion was changed to Zn(II) ion under the same condition, two-dimensional covalent complex 2 [Zn2(fma)2(1,10â²-phen)2]n (fma = fumatic acid) was formed. Furthermore, complex 2 exhibits intense photoluminescent property at room temperature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Research in Chinese Universities - Volume 23, Issue 3, May 2007, Pages 245-249
Journal: Chemical Research in Chinese Universities - Volume 23, Issue 3, May 2007, Pages 245-249
نویسندگان
WANG Xiao-lan, WANG En-bo, XU Xin-xin,