کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1260193 971727 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and Characterization of Some Lanthanide(III) Complexes with 4-[N-(2-methoxybenzylimine)formyl]-2, 3-dimethyl-1-phenyl-3-pyazolin-5-one
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Synthesis and Characterization of Some Lanthanide(III) Complexes with 4-[N-(2-methoxybenzylimine)formyl]-2, 3-dimethyl-1-phenyl-3-pyazolin-5-one
چکیده انگلیسی

A series of seven novel lanthanide(III) nitrato complexes with 4-[N-(2-methoxybenzylimine)formyl] 1-2, 3-dimethyl-1-phenyl-3-pyazolin-5-one (2mbfa), were synthesized. These complexes were characterized by elemental analysis, molecular mass determination, conductance and magnetic moment measurements, IR, UV-visible, and 13CNMR spectral studies. In these complexes, the Schiff base, 2mbfa, acts as neutral bidentate ligand by utilizing the carbonyl oxygen and azomethine nitrogen as donor sites. All the three nitrate ions are also coordinated unidentately with 7 coordination for the lanthanide(III) ions with a tentative monocapped octahedral geometry for the complexes. All the seven lanthanide(III) complexes have a general formula, [Ln(2mbfa)2(NO3)3].

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Rare Earths - Volume 25, Issue 6, December 2007, Pages 670-673