کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1261598 | 971821 | 2011 | 4 صفحه PDF | دانلود رایگان |
Blue-green luminescent BaAl2O4:Eu2+,Dy3+ phosphor powders were synthesized via combustion synthesis method assisted by microwave irradiation in air. The phosphors were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and fluorescence spectrophotometer. The XRD results revealed that when the concentration of urea was over 3 times higher than theoretical quantities, a BaAl2O4 single hexagonal phase was obtained. The SEM results revealed that the surface of the BaAl2O4:Eu2+,Dy3+ powder samples showed lots of voids and pores. The BaAl2O4:Eu2+,Dy3+ phosphors exhibited a broad emission band of main peak at 496 nm and a shoulder peak at 426 nm under excitation of 337 nm. The BaAl2O4:Eu2+,Dy3+ phosphors at the Eu2+ concentration of 1 mol.% showed the strongest luminescent intensity. Long afterglow phosphorescence was observed in the dark with naked eyes after the removal of the excitation source.
Journal: Journal of Rare Earths - Volume 29, Issue 4, April 2011, Pages 326-329