کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1262235 971853 2008 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation and characterization of cerium conversion coatings on magnesium alloy
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Formation and characterization of cerium conversion coatings on magnesium alloy
چکیده انگلیسی

Chemical conversion treatment by rare earth metal salt solution was considered as an alternative to chromium chemical conversion treatment to improve the corrosion resistance of magnesium alloys. In this study, cerium conversion coatings formed on AZ31 magnesium alloy were characterized and the formation mechanism was discussed. X-ray photoelectron spectroscopy (XPS) analysis showed that cerium conversion coating consisted of cerium hydroxides/oxides, in which both tetravalent cerium Ce(IV) and trivalent cerium Ce(III) species co-existed. Cerium conversion coating was a two-layer structure. Atomic force microscopy (AFM) images revealed that the morphology of the inside layer was different from that of the outside one, which was responsible for the inherent adhesive weakness of the coating. Corrosion potential (Ecorr) measurements indicated that poor adhesion limited the improvement of the corrosion resistance of the coating. During the treating process, the increased pH value of the cerium salt solution led to the precipitation of cerium hydroxides/oxides. The formation kinetics of the coating followed a parabolic curve.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Rare Earths - Volume 26, Issue 3, June 2008, Pages 383-387