کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1262690 971886 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Collapse of charge ordering in Bi0.5Sr0.5MnO3 by cation disorder: a magnetic and structural investigation
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Collapse of charge ordering in Bi0.5Sr0.5MnO3 by cation disorder: a magnetic and structural investigation
چکیده انگلیسی

The structure, transport, and magnetic properties of LaxBi0.5-xSr0.5MnO3 (LBSMO) (x=0.1 and 0.4) were studied through X-ray diffraction, magnetization, and electron spin resonance (ESR) measurements. The structural analysis showed that the LBSMO crystallized in an orthorhombic perovskite structure with Pbnm space group for x=0.1 and Imma space group for x=0.4 and the highly polarizable 6s2 lone pair of Bi3+ was the tuning factor for the structural variations. Magnetic studies revealed that the replacement of Bi ions by La ions resulted in the collapse high temperature charge ordering state of BSMO and it order Ferro Magnetically (FM) with TC around 355 and 330 K for x=0.1 and 0.4, respectively. Both ESR, temperature and field dependant magnetization suggested that there was a coexistence of FM and the paramagnetic phases well below TC and the FM and CO-AFM phases below 250 K of LBSMO.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Rare Earths - Volume 26, Issue 2, April 2008, Pages 237-240